You have a requirement to nullify (empty the value in the field) a value entered in a field in Materials. But couldn't able to do it using Mass Change functionality.
It is not possible to nullify a value of parameter in Material Master Data. This is not possible using Mass Change or Migration or through Mass Data Maintenance functionalities.
Basically, using Mass Change of Materials, Mass Data Maintenance or using Migration, you can modify a existing value or add a new value to the parameter but its not possible to nullify the values due to technical constrains.
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