Not all the request approvers are listed for the line item?
Do you see the warning message below in the request audit log?
SAP GRC Access Control 10.0
SAP GRC Access Control 10.1
Line-item '0001': Only 1st 00030 approvers (from XXXX returned) will be used, Not all, request approvers, listed, warning message, audit log, number of approvers, allowed per line item, default, 30, GRFNMW_CONFIGURE, SAP_GRAC_AR, process type, Maintain Process Global Settings (Not Versioned), Max. Appr. per LI , KBA , GRC-SAC-ARQ , Access Request , GRC-SAC-WF , Workflow , How To
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