You have noticed that the employees are able to request leaves on non working days as long as the leave has at least one working day in it.
In this case regardless of your configuration to allow requesting on non working days you are able to request leaves starting on Saturday or Sunday.
"Image/data in this KBA is from SAP internal systems, sample data, or demo systems. Any resemblance to real data is purely coincidental."
SAP SuccessFactors Employee Central (EC) - All Versions
request on non working days, weekends, request on holidays , KBA , LOD-SF-EC-TIM , Time Off , Problem
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