The configuration to use TLS authentication with SSL protocol has been performed according the SAP Note below:
1747180 - SMTP via TLS and SMTP authentication
However, during the send process, the error message XS612 - SSL peer certificate untrusted occurs:
SAP NetWeaver 7.00 or above.
KBA , BC-SRV-COM , Communication Services: Mail, Fax, SMS, Telephony , Problem
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